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En el instante 23 de junio de 2026, 16:01:36 UTC,
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Modificado el valor del campo
spatial_coverage
a[{'bbox': '{"type": "Polygon", "coordinates": [[[-2.34, 37.38], [-0.69, 37.38], [-0.69, 38.76], [-2.34, 38.76], [-2.34, 37.38]]]}', 'centroid': '{"type": "Point", "coordinates": [-1.515, 38.07]}', 'text': 'Región de Murcia', 'uri': 'http://datos.gob.es/recurso/sector-publico/territorio/Autonomia/Region-Murcia'}]
en Analysis of alcohol polyethoxylates and polyethylene glycols in marine sediments
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| 94 | "notes": "Alcohol polyethoxylates (AEOs) are the most commercially | 94 | "notes": "Alcohol polyethoxylates (AEOs) are the most commercially | ||
| 95 | important type of nonionic surfactants, used in a wide variety of | 95 | important type of nonionic surfactants, used in a wide variety of | ||
| 96 | products such as household cleaning detergents, industrial cleaners, | 96 | products such as household cleaning detergents, industrial cleaners, | ||
| 97 | textiles, adjuvants in pesticides, wetting and dispersing agents, and | 97 | textiles, adjuvants in pesticides, wetting and dispersing agents, and | ||
| 98 | emulsifiers. Our main objective in this work was to develop a | 98 | emulsifiers. Our main objective in this work was to develop a | ||
| 99 | methodology for the extraction, isolation and analysis of these | 99 | methodology for the extraction, isolation and analysis of these | ||
| 100 | compounds and their main degradation products and precursors | 100 | compounds and their main degradation products and precursors | ||
| 101 | (polyethylene glycols, PEGs) in solid environmental matrices. First, | 101 | (polyethylene glycols, PEGs) in solid environmental matrices. First, | ||
| 102 | analytes were extracted by pressurized liquid extraction (PLE) using | 102 | analytes were extracted by pressurized liquid extraction (PLE) using | ||
| 103 | methanol at 120 C as solvent and 3 cycles (5 min per cycle). Clean-up | 103 | methanol at 120 C as solvent and 3 cycles (5 min per cycle). Clean-up | ||
| 104 | and concentration of the extracts were carried out by solid-phase | 104 | and concentration of the extracts were carried out by solid-phase | ||
| 105 | extraction (SPE), using Oasis HLB cartridges and a mixture | 105 | extraction (SPE), using Oasis HLB cartridges and a mixture | ||
| 106 | dicloromethane/methanol 1:1 as eluting solvent. Recovery percentages | 106 | dicloromethane/methanol 1:1 as eluting solvent. Recovery percentages | ||
| 107 | were usually between 54% and 106% for most compounds. Identification | 107 | were usually between 54% and 106% for most compounds. Identification | ||
| 108 | and quantification of analytes were performed using a liquid | 108 | and quantification of analytes were performed using a liquid | ||
| 109 | chromatography-mass spectrometry (LC-MS) system equipped with an | 109 | chromatography-mass spectrometry (LC-MS) system equipped with an | ||
| 110 | electrospray interface (ESI) operating in positive ionization mode. | 110 | electrospray interface (ESI) operating in positive ionization mode. | ||
| 111 | Water content, cone voltage and adduct formation were optimized to | 111 | Water content, cone voltage and adduct formation were optimized to | ||
| 112 | this end. Limits of detection were usually below 50 ng g(-1), being | 112 | this end. Limits of detection were usually below 50 ng g(-1), being | ||
| 113 | higher for some shorter ethoxymers ( > 100 ng g(-1)) because of poor | 113 | higher for some shorter ethoxymers ( > 100 ng g(-1)) because of poor | ||
| 114 | ionization. Finally, the protocol proposed here was applied to the | 114 | ionization. Finally, the protocol proposed here was applied to the | ||
| 115 | determination of the concentration of AEOs and PEGs in selected | 115 | determination of the concentration of AEOs and PEGs in selected | ||
| 116 | surface sediment samples collected in Mar Menor Lagoon (Murcia, | 116 | surface sediment samples collected in Mar Menor Lagoon (Murcia, | ||
| 117 | Spain). In this sense, this paper presents some of the first data | 117 | Spain). In this sense, this paper presents some of the first data | ||
| 118 | relative to the occurrence of these analytes in coastal sediments, | 118 | relative to the occurrence of these analytes in coastal sediments, | ||
| 119 | showing relatively high concentrations of PEGs (up to 9000 ng g(-1)) | 119 | showing relatively high concentrations of PEGs (up to 9000 ng g(-1)) | ||
| 120 | compared to those measured for AEOs ( < 100 ng g(-1)). (C) 2013 | 120 | compared to those measured for AEOs ( < 100 ng g(-1)). (C) 2013 | ||
| 121 | Elsevier B.V. All rights reserved.", | 121 | Elsevier B.V. All rights reserved.", | ||
| 122 | "notes_translated": { | 122 | "notes_translated": { | ||
| 123 | "es": "Alcohol polyethoxylates (AEOs) are the most commercially | 123 | "es": "Alcohol polyethoxylates (AEOs) are the most commercially | ||
| 124 | important type of nonionic surfactants, used in a wide variety of | 124 | important type of nonionic surfactants, used in a wide variety of | ||
| 125 | products such as household cleaning detergents, industrial cleaners, | 125 | products such as household cleaning detergents, industrial cleaners, | ||
| 126 | textiles, adjuvants in pesticides, wetting and dispersing agents, and | 126 | textiles, adjuvants in pesticides, wetting and dispersing agents, and | ||
| 127 | emulsifiers. Our main objective in this work was to develop a | 127 | emulsifiers. Our main objective in this work was to develop a | ||
| 128 | methodology for the extraction, isolation and analysis of these | 128 | methodology for the extraction, isolation and analysis of these | ||
| 129 | compounds and their main degradation products and precursors | 129 | compounds and their main degradation products and precursors | ||
| 130 | (polyethylene glycols, PEGs) in solid environmental matrices. First, | 130 | (polyethylene glycols, PEGs) in solid environmental matrices. First, | ||
| 131 | analytes were extracted by pressurized liquid extraction (PLE) using | 131 | analytes were extracted by pressurized liquid extraction (PLE) using | ||
| 132 | methanol at 120 C as solvent and 3 cycles (5 min per cycle). Clean-up | 132 | methanol at 120 C as solvent and 3 cycles (5 min per cycle). Clean-up | ||
| 133 | and concentration of the extracts were carried out by solid-phase | 133 | and concentration of the extracts were carried out by solid-phase | ||
| 134 | extraction (SPE), using Oasis HLB cartridges and a mixture | 134 | extraction (SPE), using Oasis HLB cartridges and a mixture | ||
| 135 | dicloromethane/methanol 1:1 as eluting solvent. Recovery percentages | 135 | dicloromethane/methanol 1:1 as eluting solvent. Recovery percentages | ||
| 136 | were usually between 54% and 106% for most compounds. Identification | 136 | were usually between 54% and 106% for most compounds. Identification | ||
| 137 | and quantification of analytes were performed using a liquid | 137 | and quantification of analytes were performed using a liquid | ||
| 138 | chromatography-mass spectrometry (LC-MS) system equipped with an | 138 | chromatography-mass spectrometry (LC-MS) system equipped with an | ||
| 139 | electrospray interface (ESI) operating in positive ionization mode. | 139 | electrospray interface (ESI) operating in positive ionization mode. | ||
| 140 | Water content, cone voltage and adduct formation were optimized to | 140 | Water content, cone voltage and adduct formation were optimized to | ||
| 141 | this end. Limits of detection were usually below 50 ng g(-1), being | 141 | this end. Limits of detection were usually below 50 ng g(-1), being | ||
| 142 | higher for some shorter ethoxymers ( > 100 ng g(-1)) because of poor | 142 | higher for some shorter ethoxymers ( > 100 ng g(-1)) because of poor | ||
| 143 | ionization. Finally, the protocol proposed here was applied to the | 143 | ionization. Finally, the protocol proposed here was applied to the | ||
| 144 | determination of the concentration of AEOs and PEGs in selected | 144 | determination of the concentration of AEOs and PEGs in selected | ||
| 145 | surface sediment samples collected in Mar Menor Lagoon (Murcia, | 145 | surface sediment samples collected in Mar Menor Lagoon (Murcia, | ||
| 146 | Spain). In this sense, this paper presents some of the first data | 146 | Spain). In this sense, this paper presents some of the first data | ||
| 147 | relative to the occurrence of these analytes in coastal sediments, | 147 | relative to the occurrence of these analytes in coastal sediments, | ||
| 148 | showing relatively high concentrations of PEGs (up to 9000 ng g(-1)) | 148 | showing relatively high concentrations of PEGs (up to 9000 ng g(-1)) | ||
| 149 | compared to those measured for AEOs ( < 100 ng g(-1)). (C) 2013 | 149 | compared to those measured for AEOs ( < 100 ng g(-1)). (C) 2013 | ||
| 150 | Elsevier B.V. All rights reserved." | 150 | Elsevier B.V. All rights reserved." | ||
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